Studies on mgni-based metal hydride electrode with aqueous electrolytes composed of various hydroxides

Abstract

Compositions of MgNi-based amorphous-monocrystalline thin films produced by radio frequency (RF) sputtering with a varying composition target have been optimized. The composition Mg52Ni39Co3Mn6 is identified to possess the highest initial discharge capacity of 640 mAh·g−1 with a 50 mA·g−1 discharge current density. Reproduction in bulk form of Mg52Ni39Co3Mn6 alloy composition was prepared through a combination of melt spinning (MS) and mechanical alloying (MA), shows a sponge-like microstructure with >95% amorphous content, and is chosen as the metal hydride (MH) alloy for a sequence of electrolyte experiments with various hydroxides including LiOH, NaOH, KOH, RbOH, CsOH, and (C2H5)4N(OH). The electrolyte conductivity is found to be closely related to cation size in the hydroxide compound used as 1 M additive to the 4 M KOH aqueous solution. The degradation performance of Mg52Ni39Co3Mn6 alloy through cycling demonstrates a strong correlation with the redox potential of the cation in the alkali hydroxide compound used as 1 M additive to the 5 M KOH aqueous solution. NaOH, CsOH, and (C2H5)4N(OH) additions are found to achieve a good balance between corrosion and conductivity performances.