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Aromatic Substitution of Olefins. XX. Reactions of Triphenylamine, -phosphine, -arsine, -stibine, and -bismuth with Styrene in the Presence of Palladium(II) Salts

  • Asano R
  • Moritani I
  • Fujiwara Y
  • et al.
Bulletin of the Chemical Society of Japan (1973) 46(9) 2910-2911
DOI: 10.1246/bcsj.46.2910
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Abstract

Ph3P, Ph3As, Ph3Sb, and Ph3Bi reacted with PhCH:CH2 in the presence of Pd(OAc)2 to give trans-stilbene (I). Ph3N reacted with PhCH:CH2 to give trans-4-(Ph2N)C6H4CH:CHPh. In the formation of I, the order of reactivity was Ph3As > Ph3Sb ≃ Ph3N > Ph3Bi > Ph3N. [on SciFinder(R)]

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Asano, R., Moritani, I., Fujiwara, Y., & Teranishi, S. (1973). Aromatic Substitution of Olefins. XX. Reactions of Triphenylamine, -phosphine, -arsine, -stibine, and -bismuth with Styrene in the Presence of Palladium(II) Salts. Bulletin of the Chemical Society of Japan, 46(9), 2910–2911. https://doi.org/10.1246/bcsj.46.2910

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