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Well-Defined and Robust Rhodium Catalysts for the Hydroacylation of Terminal and Internal Alkenes

Angewandte Chemie - International Edition (2015) 54(29) 8520-8524
DOI: 10.1002/anie.201503208
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Abstract

A Rh-catalyst system based on the asymmetric ligand tBu2PCH2P(o-C6H4OMe)2 is reported that allows for the hydroacylation of challenging internal alkenes with β-substituted aldehydes. Mechanistic studies point to the stabilizing role of both excess alkene and the OMe-group.

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Prades, A., Fernández, M., Pike, S. D., Willis, M. C., & Weller, A. S. (2015). Well-Defined and Robust Rhodium Catalysts for the Hydroacylation of Terminal and Internal Alkenes. Angewandte Chemie - International Edition, 54(29), 8520–8524. https://doi.org/10.1002/anie.201503208

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