Abstract
Tuned to the right network: Chiral, heterometallic coordination polymers can be prepared readily by using the chiral (2S,3S)-1,2,3,4-butanetetramine, a labile, divalent transition-metal cation such as Cu2+, and an oligonuclear, rhenium-chalcogenide-cyano cluster as starting materials (see picture).
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Mironov, Y. V., Naumov, N. G., Brylev, K. A., Efremova, O. A., Fedorov, V. E., & Hegetschweiler, K. (2004). Rhenium-chalcogenide-cyano clusters, Cu2+ ions, and 1,2,3,4-tetraaminobutane as molecular building blocks for chiral coordination polymers. Angewandte Chemie - International Edition, 43(10), 1297–1300. https://doi.org/10.1002/anie.200351595
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