Chlorine anion encapsulation by molecular capsules based on cucurbit[5]uril and decamethylcucurbit[5]uril

Abstract

Three barrel-shaped artificial molecular capsules 1-3, based on normal cucurbit[5]uril (Q[5]) and decamethylcucurbit[5]uril (Me10Q[5]), were synthesized and structurally characterized by single-crystal X-ray diffraction. Encapsulation of a chlorine anion in the cavity of a Q[5] or Me 10Q[5] to form closed a molecular capsule with the coordinated metal ions or coordinated metal ions and water molecules in the crystal structures of these compounds is common. The three complexes [Pr2(C 30H30N20O10)Cl3(H 2O)13]3+3Cl-·5H2O (1), [Sr2(C40H50N20O 10)(H2O)4Cl]3+3Cl -·2(HCl) 19H2O (2) and [K(C40H 50N20O10)(H2O)Cl]·[Zn(H 2O)2Cl2]·[ZnCl4] 2-·2(H3O)+·8H2O (3) all crystallize as isolated molecular capsules. © 2007 by MDPI.