Isolation and phototransformation of enantiomerically pure iridium(III) bis[(4,6-difluorophenyl)pyridinato-N,C2]picolinate

Yue Wang; Takunori Harada; Yoshihito Shiota; Kazunari Yoshizawa; Heng Wang; Sheng Wang; Xichong Ye; Masamichi Ogasawara; Tamaki Nakano

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Isolation and phototransformation of enantiomerically pure iridium(III) bis[(4,6-difluorophenyl)pyridinato-N,C2]picolinate

RSC Advances (2017) 7(47) 29550-29553

DOI: 10.1039/c7ra04141a

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Abstract

Here we report the resolution of phosphorescent light-emitting iridium(iii) bis[(4,6-difluorophenyl)pyridinato-N,C2]-picolinate into its respective enantiomers by using chiral HPLC and the photo-induced transformation of the isolated enantiomers.

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Wang, Y., Harada, T., Shiota, Y., Yoshizawa, K., Wang, H., Wang, S., … Nakano, T. (2017). Isolation and phototransformation of enantiomerically pure iridium(III) bis[(4,6-difluorophenyl)pyridinato-N,C2]picolinate. RSC Advances, 7(47), 29550–29553. https://doi.org/10.1039/c7ra04141a

Isolation and phototransformation of enantiomerically pure iridium(III) bis[(4,6-difluorophenyl)pyridinato-N,C2]picolinate

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