Branched tetrasilane substituted phosphines - synthesis and characterisation of PhSi(SiiPr2)3P and (PhSi(SiMe2)3)2P14

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Abstract

The branched trichlorotetrasilane PhSi(SiMe2Cl)3 reacts with P7(SiMe3)3 leading to formation of a new oligophosphane (PhSi(SiMe2)3)2P14 (1), which consists of two PhSi(SiMe2)3 substituted P7 norbornane units. The phosphatetrasila[1.1.1]pentane derivative PhSi(SiiPr2)3P (3) was obtained from the reaction of PhSi(SiiPr2Cl)3 (2) with Li3P. © 2014 Partner Organisations.

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Feierabend, M., & Von Hänisch, C. (2014). Branched tetrasilane substituted phosphines - synthesis and characterisation of PhSi(SiiPr2)3P and (PhSi(SiMe2)3)2P14. Chemical Communications, 50(34), 4416–4419. https://doi.org/10.1039/c4cc00165f

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