Abstract
Significant differences in the reactivity of norbornene derivatives in the inverse electron-demand Diels-Alder reaction with tetrazines were revealed by kinetic studies. Substantial rate enhancement for the exo norbornene isomers was observed (see scheme). Quantum-chemical calculations were used to rationalize and support the observed experimental data. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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Vrabel, M., Kölle, P., Brunner, K. M., Gattner, M. J., Lõpez-Carrillo, V., De Vivie-Riedle, R., & Carell, T. (2013). Norbornenes in inverse electron-demand diels-alder reactions. Chemistry - A European Journal, 19(40), 13309–13312. https://doi.org/10.1002/chem.201301838
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