Crystal structure re-determination, spectroscopy, and photoluminescence of π-YBO3:Eu3+

Abstract

To unambiguously clarify the long-debated crystal structure of the low-temperature orthoborate π-YBO3, single-crystals of the europium-doped π-YBO3:Eu3+ were prepared via a high-pressure/high-temperature route at 7.5 GPa and 1400 °C. The structure was solved and refined in the monoclinic space group C2/c (no. 15) in the pseudowollastonite structure type, with the lattice parameters a=11.3407(5), b=6.5501(3), c=9.5798(4) Å, and β=113.08(2)°. This structure determination was corroborated by powder X-ray diffraction and vibrational spectroscopy. 11B as well as 89Y MAS NMR spectroscopy was used to verify that our results are also accurate for the undoped π-YBO3 and samples with varying europium content prepared under ambient pressure conditions. Additionally, the luminescence properties of the Eu3+ doped π-orthoborate were determined in comparison with these ambient-pressure samples.