Extraction-chromogenic system for nickel(II) based on 5-methyl-4-(2-thiazolylazo)resorcinol and Aliquat 336

Abstract

A water−isobutanol extraction-chromogenic system for NiII, based on the azo dye 5-methyl-4-(2-thiazolylazo)resorcinol (MTAR; H2L) and the ionic liquid Aliquat 336 (A336), was studied. Under the optimal conditions (cMTAR = 2.0 × 10-4 mol dm-3, cA336 = 5.6 × 10-3 mol dm-3, pH 8.5 and extraction time t = 1 min), NiII is extracted as a ternary complex which can be represented by the formula (A336+)2[Ni(L2−)2]. In the absence of A336, or in a slightly acidic medium, a binary complex, [Ni(HL−)2], with an absorption maximum at λ = 548 nm and a shoulder at 590 nm is formed. The following extraction-spectrophotometric characteristics were determined at the above-mentioned optimal conditions: λmax (545 nm), molar absorptivity (5.0 × 104 dm3 mol-1 cm-1), Sandell's sensitivity (1.2 × 10-3 μg cm-2), Beer's law limits (0.05-3.1 µg cm-3), constant of extraction (Log K = 6.1) and fraction extracted (99.2%). The effect of foreign ions was studied; the most serious interferences were caused by CoII, CuII and CrIII.