Direct synthesis of the Janus-head ligand (MePy)3Sn-Sn(MePy)3 using an unusual pyridyl-transfer reaction (MePy = 6-methyl-2-pyridyl)

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Abstract

The in situ reaction of the tripodal anion [EtAl(MePy)3]- (MePy = 6-Me-2-py) with SnCl2 gives the Janus-head ligand (MePy)3Sn-Sn(MePy)3, containing a Sn-Sn bond, through a novel, one-pot reaction involving a combination of pyridyl transfer and metal-oxidation. This journal is

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García-Rodríguez, R., & Wright, D. S. (2014). Direct synthesis of the Janus-head ligand (MePy)3Sn-Sn(MePy)3 using an unusual pyridyl-transfer reaction (MePy = 6-methyl-2-pyridyl). Dalton Transactions, 43(39), 14529–14532. https://doi.org/10.1039/c4dt02216e

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