Peroxide Anions as Possible Active Species in Oxidative Coupling of Methane

  • Otsuka K
  • Said A
  • Jinno K
  • et al.
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Abstract

Oxidative coupling of CH4 forming C2H6 and C2H4 proceeded smoothly upon contact with Na2O2, BaO2, and SrO2 at low temperatures below 673 K. This indicates that O22− ions are very reactive for activation of CH4. O2− ions contained in the peroxides did not activate CH4.

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Otsuka, K., Said, A. A., Jinno, K., & Komatsu, T. (1987). Peroxide Anions as Possible Active Species in Oxidative Coupling of Methane. Chemistry Letters, 16(1), 77–80. https://doi.org/10.1246/cl.1987.77

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