Anion-assisted supramolecular polymerization: From achiral AB-type monomers to chiral assemblies

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Abstract

Anions do make a difference! Counterions released during the acid-promoted self-assembly of AB-type monomer precursors dock into designated ancillary binding sites and thus facilitate the polymerization process while transferring their molecular properties to the entire supramolecular structure (see picture). Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Capici, C., Cohen, Y., D’Urso, A., Gattuso, G., Notti, A., Pappalardo, A., … Villari, V. (2011). Anion-assisted supramolecular polymerization: From achiral AB-type monomers to chiral assemblies. Angewandte Chemie - International Edition, 50(50), 11956–11961. https://doi.org/10.1002/anie.201104357

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