A green approach to ethyl acetate: Quantitative conversion of ethanol through direct dehydrogenation in a Pd-Ag membrane reactor

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Abstract

Pincers do the trick: The conversion of ethanol to ethyl acetate and hydrogen was achieved using a pincer-Ru catalyst in a Pd-Ag membrane reactor. Near quantitative conversions and yields could be achieved without the need for acid or base promoters or hydrogen acceptors (see scheme). © 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Zeng, G., Chen, T., He, L., Pinnau, I., Lai, Z., & Huang, K. W. (2012). A green approach to ethyl acetate: Quantitative conversion of ethanol through direct dehydrogenation in a Pd-Ag membrane reactor. Chemistry - A European Journal, 18(50), 15940–15943. https://doi.org/10.1002/chem.201202005

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