Homologous series of extended oligomeric and polymeric π-chains with arylene and arylenevinylene repeating units are investigated as a function of the chain length. Depending upon the nature of the building blocks and the mode of linking the chain-length dependance leads to fundamentally different chemical and physical consequences. An increase in dimensionality appears as a crucial step in the design and synthesis of molecular and supramolecular structures. © 1993 IUPAC
CITATION STYLE
Müllen, K. (1993). Extended π-systems in conjugated oligomers and polymers—the longer, the better? Pure and Applied Chemistry, 65(1), 89–96. https://doi.org/10.1351/pac199365010089
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