Impedance spectroscopy analysis of double perovskite Ho 2NiTiO6

Abstract

The electrical properties of double perovskite Ho2NiTiO 6 (HNT) are investigated by impedance spectroscopy in the temperature range 30-420 °C and frequency range 100 Hz to 1 MHz. The X-ray diffraction analysis reveals that the compound crystallizes in monoclinic phase. The imaginary part of impedance (Z″) as a function of frequency shows Debye type relaxation. The frequency dependence of Z″ peak is found to obey an Arrhenius law with an activation energy of 0.129 eV. Impedance data presented in the Nyquist plot (Z″ vs. Z′) are used to identify an equivalent circuit and to know the bulk and interface contributions. The complex impedance analysis of HNT exhibits the appearance of both the grain and grain-boundary contribution. The results of bulk ac conductivity as a function of temperature and frequency are presented. The activation energy (0.129 eV), calculated from the slope of log τ versus 103/T plot, is found to be the nearly same as calculated (0.130 eV) from dc conductivity. The frequency dependent conductivity spectra obey the power law. © 2010 The Author(s).