Rotaxane building blocks bearing blocked isocyanate stoppers: Polyrotaxanes through post-assembly chain extension

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Abstract

A simple versatile route to polyrotaxanes with a variety of topologies is described through the synthesis and subsequent polymerization of readily accessible and stable rotaxane monomers containing bulky blocked isocyanate stopper groups.

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Kidd, T. J., Loontjens, T. J. A., Leigh, D. A., & Wong, J. K. Y. (2003). Rotaxane building blocks bearing blocked isocyanate stoppers: Polyrotaxanes through post-assembly chain extension. Angewandte Chemie - International Edition, 42(29), 3379–3383. https://doi.org/10.1002/anie.200351458

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