Low temperature activation of methane over a zinc-exchanged heteropolyacid as an entry to its selective oxidation to methanol and acetic acid

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Abstract

A Zn-exchanged heteropolyacid supported onto silica (Zn-HPW/SiO2) activates methane at 25 °C into Zn-methyl. At higher temperatures and with CH4/O2 or CH4/CO2, it gives methanol and acetic acid respectively. © 2014 The Partner Organisations.

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Patil, U., Saih, Y., Abou-Hamad, E., Hamieh, A., Pelletier, J. D. A., & Basset, J. M. (2014). Low temperature activation of methane over a zinc-exchanged heteropolyacid as an entry to its selective oxidation to methanol and acetic acid. Chemical Communications, 50(82), 12348–12351. https://doi.org/10.1039/c4cc04950k

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