Application of microwave in hydrogen production from methane dry reforming: Comparison between the conventional and microwave-assisted catalytic reforming on improving the energy efficiency

Abstract

The microwave-assisted dry reforming of methane over Ni and Ni–MgO catalysts supported on activated carbon (AC) was studied with respect to reducing reaction energy consumption. In order to optimize the reforming reaction using the microwave setup, an inclusive study was performed on the effect of operating parameters, including the type of catalysts’ active metal and their concentration in the AC support, feed flow rate, and reaction temperature on the reaction conversion and H2 /CO selectivity. The methane dry reforming was also carried out using conventional heating and the results were compared to those of microwave heating. The catalysts’ activity was increased under microwave heating and as a result, the feed conversion and hydrogen selectivity were enhanced in comparison to the conventional heating method. In addition, to improve the reactants’ conversion and products’ selectivity, the thermal analysis also clarified the crucial importance of microwave heating in enhancing the energy efficiency of the reaction compared to the conventional heating.