Abstract
The silica-supported azazirconacyclopropane ≡SiOZr(HNMe2)(η2-NMeCH2)(NMe2) (1) leads exclusively under hydrogenolysis conditions (H2, 150°C) to the single-site monopodal monohydride silica-supported zirconium species ≡SiOZr(HNMe2)(NMe2)2H (2). Reactivity studies by contacting compound 2 with ethylene, hydrogen/ethylene, propene, or hydrogen/propene, at a temperature of 200°C revealed alkene hydrogenation.
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Hamzaoui, B., El Eter, M., Abou-Hamad, E., Chen, Y., Pelletier, J. D. A., & Basset, J. M. (2015). Well-defined single-site monohydride silica-supported zirconium from azazirconacyclopropane. Chemistry - A European Journal, 21(11), 4294–4299. https://doi.org/10.1002/chem.201405788
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