(7E)-5-Benzyl-7-(2-chlorobenzylidene)-3-(2-chlorophenyl)-2-phenyl-3,3a,4,5, 6,7-hexahydro-2H-pyrazolo-[4,3-c]pyridine

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Abstract

In the title 2H-pyrazolo-[4,3-c]pyridine derivative, C32H 27Cl2N3, the dihydro-pyrazole ring adopts an envelope conformation and the piperidine fused ring a twisted-chair conformation. Two short intra-molecular C-H⋯Cl contacts are observed. The crystal packing is characterized by dimeric C-Cl⋯π inter-actions involving the 5-benzyl ring, with Cl⋯centroid and closest atomic Cl⋯π distances of 3.778 (2) and 3.366 (4) Å, respectively.

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Karthikeyan, N. S., Mahesh, B. U., Sathiyanarayanan, K., Raghavaiah, P., & Rathore, R. S. (2010). (7E)-5-Benzyl-7-(2-chlorobenzylidene)-3-(2-chlorophenyl)-2-phenyl-3,3a,4,5, 6,7-hexahydro-2H-pyrazolo-[4,3-c]pyridine. Acta Crystallographica Section E: Structure Reports Online, 66(7). https://doi.org/10.1107/S1600536810023317

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