From Cellulose to Highly Aromatic Hydrochar: Catalytic Carbonization and Catalytic Aromatization Mechanism of Lanthanide (III) Ions

Abstract

Hydrothermal carbonization (HTC) is an efficient method for converting lignocellulosic biomass into biofuels. However, traditional Brønsted acid-catalyzed HTC processes face challenges such as high costs and limited catalytic efficiency. In this study, the catalytic carbonization mechanism was investigated within the temperature range of 180–220 °C by analyzing the evolution of functional groups in hydrochar under lanthanide (III)-catalyzed and non-catalyzed conditions. The results indicate that compared to acid catalysis, lanthanide (III) exhibits superior catalytic performance during the low-temperature HTC of cellulose. At 200 °C, lanthanide (III) accelerates the conversion of cellulose into char microparticles, while at 220 °C, it promotes the complete hydrolysis of cellulose into char microparticles enriched with furan structures. Characterization analyses revealed that lanthanide (III) enhances the formation of HMF (5-hydroxymethylfurfural), suppresses its conversion to LA (levulinic acid), promotes the polymerization of HMF into char microparticles, and indirectly accelerates the hydrolysis of cellulose into oligosaccharides.