Abstract
A water-stable FeIV clathrochelate complex catalyses fast and homogeneous photochemical oxidation of water to dioxygen with a turnover frequency of 2.27 s-1 and a maximum turnover number of 365. An FeV intermediate generated under catalytic conditions is trapped and characterised using EPR and Mössbauer spectroscopy.
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CITATION STYLE
APA
Shylin, S. I., Pavliuk, M. V., D’Amario, L., Mamedov, F., Sá, J., Berggren, G., & Fritsky, I. O. (2019). Efficient visible light-driven water oxidation catalysed by an iron(iv) clathrochelate complex. Chemical Communications, 55(23), 3335–3338. https://doi.org/10.1039/c9cc00229d
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