Synthesis and two-photon absorption of triphenylbenzene-cored dendritic chromophores

Abstract

The synthesis and the characterization of triphenylbenzene-cored dendrimers of first- and second-generation are described. Their absorption, photoluminescence as well as their two-photon absorption properties have been investigated and compared to a quadrupolar counterpart. These molecules combine wide transparency in the visible range and high two-photon absorption cross-sections that increase with the generation, making these dendrimers promising systems for optical power limiting applications. © 2003 Elsevier Science Ltd. All rights reserved.