Towards selective ethylene tetramerization

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Abstract

And the magic number is... . A large amount of oligomer-free 1-octene (99.9%) was produced from ethylene by a catalytic system based on chromium during the formation of polyethylene wax [see GC-MS chromatogram; the other three significant peaks are methanol (quenching agent), ethyl acetate (needle-rinsing agent), and toluene (solvent)]. Copyright © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Licciulli, S., Thapa, I., Albahily, K., Korobkov, I., Gambarotta, S., Duchateau, R., … Schuhen, K. (2010). Towards selective ethylene tetramerization. Angewandte Chemie - International Edition, 49(48), 9225–9228. https://doi.org/10.1002/anie.201003465

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