Abstract
(Chemical Equation Presented) On the same route: Chromium-carbyne complexes are readily prepared by treatment of 1,1,1-trichloromethyl reagents with chromium(II) chloride. They serve as intermediates in the selective formation of a wide variety of products, such as alkynes, alkenes, β-hydroxy ketones, aldehydes, allylic alcohols, and allenes (see scheme, E = electrophile). © 2007 Wiley-VCH Verlag GmbH S. Co. KGaA.
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Bejot, R., He, A., Falck, J. R., & Mioskowski, C. (2007). Chromium-carbyne complexes: Intermediates for organic synthesis. Angewandte Chemie - International Edition, 46(10), 1719–1722. https://doi.org/10.1002/anie.200604015
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