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CYCLOADDITION OF STABLE DISILENES TO TERMINAL ACETYLENES

  • Young D
  • West R
Chemistry Letters (1986) 15(6) 883-884
DOI: 10.1246/cl.1986.883
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Abstract

Tetramesityldisilene and trans-1,2-di-t-butyl-1,2-dimesityldisilene (3) react with various 1-alkynes to give air-stable disilacyclobutenes. The cycloaddition of 3 to alkynes produces equal amounts of both stereoisomers, consistent with a stepwise mechanism.

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Young, D. J. D., & West, R. (1986). CYCLOADDITION OF STABLE DISILENES TO TERMINAL ACETYLENES. Chemistry Letters, 15(6), 883–884. https://doi.org/10.1246/cl.1986.883

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