New Light on Molecule–Nanotube Hybrids

Abstract

Optoelectronics benefits from outstanding new nanomaterials that provide emission and detection in the visible and near-infrared range, photoswitches, two level systems for single photon emission, etc. Among these, carbon nanotubes are envisioned as game changers despite difficult handling and control over chirality burdening their use. However, recent breakthroughs on hybrid carbon nanotubes have established nanotubes as pioneers for a new family of building blocks for optics and quantum optics. Functionalization of carbon nanotubes with molecules or polymers not only preserves the nanotube properties from the environment, but also promotes new performance abilities to the resulting hybrids. Photoluminescence and Raman signals are enhanced in the hybrids, which questions the nature of the electronic coupling between nanotube and molecules. Furthermore, coupling to optical cavities dramatically enhances single photon emission, which operates up to room temperature. This new light on nanotube hybrids shows their potential to push optoelectronics a step forward.