Gold-catalyzed cyclization/oxidative [3+2] cycloadditions of 1,5-enynes with nitrosobenzenes without additional oxidants

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Abstract

Golden control: The title reaction (see scheme) proceeds with high stereocontrol to generate the heterocyclic products in good yield. Experiments to probe the mechanism were performed. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Chen, C. H., Tsai, Y. C., & Liu, R. S. (2013). Gold-catalyzed cyclization/oxidative [3+2] cycloadditions of 1,5-enynes with nitrosobenzenes without additional oxidants. Angewandte Chemie - International Edition, 52(17), 4599–4603. https://doi.org/10.1002/anie.201209850

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