Confinement effects on optical phonons in spherical, rod-, and tetrapod-shaped nanocrystals detected by Raman spectroscopy

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Abstract

Spherical, rod- and tetrapod shaped CdSe nanocrystals are investigated by Raman spectroscopy and the longitudinal-optical and surface optical phonons are observed. We find that the position of the longitudinal-optical phonon slightly red-shifts with decreasing diameter, whereas the position of the surface optical phonon depends significantly on diameter and length of the rods or the tetrapod arms. © 2007 WILEY-VCH Verlag GmbH & Co. KGaA.

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Nobile, C., Kudera, S., Fiore, A., Carbone, L., Chilla, G., Kipp, T., … Krahne, R. (2007). Confinement effects on optical phonons in spherical, rod-, and tetrapod-shaped nanocrystals detected by Raman spectroscopy. In Physica Status Solidi (A) Applications and Materials Science (Vol. 204, pp. 483–486). https://doi.org/10.1002/pssa.200673223

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