Synthesis of gold nanoparticles of variable morphologies using aqueous leaf extracts of Cocculus hirsutus

Abstract

Spherical, triangular (prismatic) and square plate shaped gold nanoparticles have been synthesised from HAuCl 4 · 3H 2O solution using the aqueous leaf extract of Cocculus hirsutus. Nanoparticles are characterised using higher resolution transmission electron microscope, X-ray diffraction and UV-Vis absorption spectroscopic study. FT-IR analysis reveals that the gold nanostructures are mostly stabilised by the carbonyl and amide groups present in the active component of C. hirsutus leaf extract. Formation of gold nanostructures of variable morphologies has been explained due to slow reduction of gold ions by the mild reducing ascorbic acid present within the extract and this controlled reduction assists the preferential deposition of Au atom on different lesser-protected faces of initially grown gold nanostructure. © 2012 Copyright Taylor and Francis Group, LLC.