Impact of Natural and Synthetic Antioxidants on the Stability of High-Density Polyethylene

Abstract

High-Density Polyethylene (HDPE) plays a crucial role in the life of every human being due to its properties such as chemical resistance, light weight, and ease of forming, among others. Its usage ranges from bottles for beverages and other liquids, to pipes, wire and cable insulation, and prosthetics. As it undergoes several thermal cycles during its life cycle, it is essential to maintain its qualities, even after undergoing thermal and thermo-oxidative degradation. Here, various dosages of synthetic (Irganox 1010) and natural (vitamin E) antioxidants are added to HDPE formulations to study their impacts on HDPE stability. The antioxidants are mixed physically with HDPE before the mixtures are melt-mixed three times to represent their life cycles. Samples are taken after each time and used to analyze the molecular weight distribution, rheological behavior, mechanical properties, and thermal stability. The results show that vitamin E is superior to Irganox 1010 in these tests, as vitamin E performance exceeds that of Irganox 1010, even at lower doses. The only drawback of using vitamin E is the yellow color it causes, which may necessitate the addition of another additive to enhance the color stability of HDPE in color-sensitive applications.