Terminology and conventions for microelectronic ion-selective field effect transistor devices in electrochemistry (IUPAC Recommendations 1994)

Abstract

In anticipation of the widespread use of Ion-Selective Field Effect Transistors (ISFETs) in electrochemistry and analytical chemistry it is appropriate to make recommendations about terminology and presentation of results. The terms gate voltage, drain current and gate bias potential are defined and experimental techniques for measurements with ISFETs are summarised. The output signal is usually a potential difference whose magnitude varies with change in logarithm of sensed ion activity or concentration in the same way (but not necessarily in sign) as the corresponding ion-selective electrode (ISE). It is proposed that the graphical representation of results should be in accordance with previously made recommendations for ISEs, that is, that the output potential difference be plotted so that variation with increase of logarithm of activity or concentration has a positive slope for cation-responsive devices and a negative slope for anion-responsive devices. © 1994, Walter de Gruyter. All rights reserved.