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Isolable phosphanylidene phosphorane with a sterically accessible two-coordinate phosphorus atom

Angewandte Chemie - International Edition (2012) 51(40) 10150-10153
DOI: 10.1002/anie.201204998
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Abstract

'P' undressed: A stable phosphanylidene phosphorane with a sterically accessible (naked) two-coordinate P is reported (see structure). Coordination to Pd 0 reveals its phosphine donor/phosphinidene acceptor (R 3P→PR') nature by exposing its phosphinidene-like reactivity. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Surgenor, B. A., Bühl, M., Slawin, A. M. Z., Woollins, J. D., & Kilian, P. (2012). Isolable phosphanylidene phosphorane with a sterically accessible two-coordinate phosphorus atom. Angewandte Chemie - International Edition, 51(40), 10150–10153. https://doi.org/10.1002/anie.201204998

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