Highly Concentrated Hydroxyapatite Suspension for DLP Printing

Abstract

Due to the lack of commercially available high-quality hydroxyapatite (HA) powder, it is still rarely reported by the literature concerning the development of UV resin for digital light processing 3D printing. The previous studies still had the problem of delamination and also poor sintering performance led by low solid-load slurry. Here low viscosity and high solid-load hydroxyapatite (HA) UV resin suspensions were developed for digital light processing 3D printing. In this study, the effect of the type of dispersant, the dose levels of dispersant and the solid load of HA powder on the rheology properties were thoroughly investigated to obtain a flowable highly-concentrated HA UV resin suspension. Finally, a 40vol% slurry with viscosity of 3.7Pa•s at a shear rate of 10 s-1 was successfully developed. After 3D printing and sintering, a dense ceramic with relative density of 95.85% can be obtained at a sintering temperature of 1300°C.