Green synthesis of magnetic activated carbon from peanut shells functionalized with TiO2 photocatalyst for Batik liquid waste treatment

Abstract

The composite of magnetic activated carbon derived from peanut shells functionalized titanium dioxide (Fe3O4/TiO2/AC) has been successfully synthesized. The composite was employed to remove indigosol green and Cr(vi) under ultraviolet (UV) and visible light. In this work, the activated carbon was synthesized from a sustainable source of peanut shell by carbonization and activation method employing NaOH as the activating agent. Magnetite was prepared by chemical co-precipitation technique using FeCl3·6H2O and FeSO4·7H2O, and then, the deposition of TiO2 was performed under ultrasonic irradiation. A variety of material characterization, consisting of Fourier transform infrared, X-ray diffraction, and scanning electron microscopy-energy dispersive X-ray, was used to analyze the physicochemical properties of the composite. The effects of pH, irradiation time, and composite mass during optimization performance were investigated. The characterizations represent the dispersed TiO2 in the anatase phase with the existence of magnetic particles. The activity tests revealed the superiority of the composite for applications involving adsorption and photocatalysis under visible light source compared to UV light. It was found that Fe3O4/TiO2/AC yields the efficiency for the removal of indigosol green and Cr(vi) from Batik liquid waste of 92.91 and 76.92%, respectively.