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Vitamin B12 and a metal-organic framework enable the photocatalytic generation of alkyl radicals

Chemical Communications (2023) 59(75) 11236-11239
DOI: 10.1039/d3cc02941g
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Abstract

A versatile Co-catalyst-vitamin B12 (cobalamin)-can be photochemically reduced to its catalytically active Co(i) form under visible light irradiation, in the presence of MIL-125-NH2(Ti) as a photocatalyst and utilized for the generation of alkyl radicals. The prior reduction of cobalamin to the Co(ii) form is not required in this method.

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Dworakowski, K. R., Chołuj, A., Chmielewski, M. J., & Gryko, D. (2023). Vitamin B12 and a metal-organic framework enable the photocatalytic generation of alkyl radicals. Chemical Communications, 59(75), 11236–11239. https://doi.org/10.1039/d3cc02941g

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