Thermal and spectroscopic properties of light lanthanides (III) and sodium complexes of 2,5-pyridinedicarboxylic acid

Abstract

Pyridine-2,5-dicarboxylic acid, known as isocinchomeric acid is one of six isomers containing two carboxylic groups. Light lanthanide (III) complexes with pyridine-2,5-dicarboxylic acid with general formula Ln 2 L 3 •nH 2 O, where n = 8, 9, were obtained. Their thermal and spectroscopic properties were studied. Sodium salt was obtained as Na 2 L•H 2 O. Hydrated complexes of La(III), Ce(III), Pr(III), Nd(III), Sm(III), Eu(III) and Gd(III) are stable to 313-333 K, whereas Na 2 L•H 2 O is stable to about 333 K. Dehydration process for all compounds runs in one stage, next they decompose into appropriate lanthanide oxalates, oxocarbonates carbonates and finally to metal oxides. Bands of νCOOH vibrations at 1736 and 1728 cm -1 disappear on complex spectra and ν as and ν s of COO - groups appear thus indicating that complexation process took place. © 2010 The Author(s).