Abstract
From the reaction of AgCCtBu with 9-hydroxy-9-fluorenecarboxylic acid (HL) and AgCF3CO2, we have isolated a new type of organosilver(I) coordination polymeric chain, namely {[Ag14(CC tBu)8(L)2(CF3CO2) 4]·2CH3OH}n, which contains centrosymmetric [Ag14(CCtBu)8(CF 3CO2)2]4 + cluster segments bridged by pairs of L and trifluoroacetate ligands. © 2013 Elsevier B.V. All rights reserved.
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Xie, Y. P., Al-Thabaiti, S. A., Mokhtar, M., & Mak, T. C. W. (2013). An unusual silver-ethynide polymeric chain containing centrosymmetric Ag14 cluster segments stabilized by mixed carboxylate ligands. Inorganic Chemistry Communications, 31, 54–57. https://doi.org/10.1016/j.inoche.2013.02.019
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