Effect of corn pre-puffing on the efficiency of MgO-engineered biochar for phosphorus recovery from livestock wastewater: mechanistic investigations and cost benefit analyses

Abstract

To improve the phosphorus (P) recovery efficiency from livestock wastewater, a novel MgO doped mildewed corn biochar with thermal pre-puffing treatment (Mg-PBC) and without pre-puffing (Mg-BC) was synthesized and tested. The thermal-puffing pretreatment improved the effectiveness of metal soaking and MgO dispersion. P recovery time with Mg-PBC (7 h) was significantly shorter than that with Mg-BC (12 h). Moreover, Mg-PBC showed significantly higher P recovery capacity (241 mg g−1) than Mg-BC (96.6 mg g−1). P recovery capacity of the Mg-PBC fitted to the Thomas model was 90.7 mg g−1, which was 4 times higher than that of Mg-BC (22.9 mg g−1) under column test conditions. The mechanisms involved in P recovery included precipitation, surface complexation, and electrostatic interaction. After adsorption, both Mg-BC and Mg-PBC showed relatively low regeneration abilities. The P loaded Mg-BC (Mg-BC-P) and Mg-PBC (Mg-PBC-P), the later particularly, obviously increased the available P content and promoted plant growth. The release of P increased with time in the Mg-PBC-P treated soil, while it decreased with time in the P fertilizer treated soil. A cost–benefit analysis revealed that thermal-puffing pretreatment greatly increased the profit of MgO doped biochar from −0.66 to 5.90 US$ kg−1. These findings highlight that biomass pre-puffing is a feasible treatment to produce MgO modified biochar and to recover P from livestock wastewater, and that the Mg-PBC-P can be used as a slow-release P fertilizer. Graphical Abstract: [Figure not available: see fulltext.]