Direct observation of supported W bis-methylidene from supported W-methyl/methylidyne species

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Abstract

Extensive solid-state NMR analyses unambiguously determine the formation of silica supported W bis-methylidene methyl species by reaction of the corresponding methyl carbyne with trimethylphosphine or a cyclic olefin. © 2014 The Partner Organisations.

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Callens, E., Abou-Hamad, E., Riache, N., & Basset, J. M. (2014). Direct observation of supported W bis-methylidene from supported W-methyl/methylidyne species. Chemical Communications, 50(31), 3982–3985. https://doi.org/10.1039/c4cc00286e

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