Low ppm atom transfer radical polymerization in (mini)emulsion systems

Abstract

In the last decade, unceasing interest in atomtransfer radical polymerization (ATRP) has been noted, especially in aqueous dispersion systems. Emulsion orminiemulsion is a preferred environment for industrial polymerization due to easier heat dissipation and lower production costs associated with the use of water as a dispersant. The main purpose of this review is to summarize ATRP methods used in emulsion media with different variants of initiating systems. A comparison of a dual over single catalytic approache by interfacial and ion pair catalysis is presented. In addition, future development directions for these methods are suggested for better use in biomedical and electronics industries.