Low energy positron annihilation study of composite reverse osmosis membranes

Abstract

Positron annihilation with a slow positron beam was applied to the characterization of composite reverse osmosis membranes. The results, obtained at different positron incident energies, indicated that the membranes are asymmetric with respect to the pore structure, consisting of a thin top layer with little porosity and an underlying thick porous layer. A relationship between the longest positron lifetime near the membrane surface and the salt rejection rate was discussed in terms of the free-volume hole size for the thin top layer.