Experimental and computational demonstration of a low-temperaturewaste to by-product conversion of u.s. oil shale semi-coke to a flue gas sorbent

Abstract

The volatility of crude oil prices incentivizes the use of domestic alternative fossil fuel sources such as oil shale. For ex situ oil shale retorting to be economically and environmentally viable, we must convert the copious amounts of semi-coke waste to an environmentally benign, useable by-product. Using acid and acid + base treatments, we increased the surface area of the semi-coke samples from 15 m2/g (pyrolyzed semi-coke) to upwards of 150 m2/g for hydrochloric acid washed semi-coke. This enhancement in porosity and surface area is accomplished without high temperature treatment, which lowers the overall energy required for such a conversion. XRD analysis confirms that chemical treatments removed the majority of dolomite while retaining other carbonate minerals and maintaining carbon contents of approximately 10%, which is greater than many fly ashes that are commonly used as sorbent materials. SO2 gas adsorption isotherm analysis determined that a double HCl treatment of semi-coke produces sorbents for flue gas treatment with higher SO2 capacities than commonly used fly ash adsorbents. Computational fluid dynamics modeling indicates that the sorbent material could be used in a fixed bed reactor to efficiently remove SO2 from the gas stream.