A single-chain magnet based on linear [MnIII2MnII] units

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Abstract

The synthesis, structural characterization and magnetic properties of a 1D coordination polymer based on a linear mixed valent [MnIII2MnII] repeating unit are described. It displays single-chain magnet (SCM) behaviour with an energy barrier of ∼38 K and represents the first example of a mixed valent Mn–carboxylate SCM with a linear architecture. © 2014 The Royal Society of Chemistry.

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Papatriantafyllopoulou, C., Zartilas, S., Manos, M. J., Pichon, C., Clérac, R., & Tasiopoulos, A. J. (2014). A single-chain magnet based on linear [MnIII2MnII] units. Chemical Communications, 50(94), 14873–14876. https://doi.org/10.1039/c4cc05687f

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