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Probing Lewis acid-base interactions in single-molecule junctions

Nanoscale (2018) 10(38) 18131-18134
DOI: 10.1039/c8nr06562d
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Abstract

A novel strategy to regulate the tunneling mechanism for charge transport through an organoborane wire via Lewis acid-base interactions has been developed. A change from LUMO- to HOMO-dominated charge transport upon the addition of the fluoride is verified both experimentally and theoretically.

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Liu, X., Li, X., Sangtarash, S., Sadeghi, H., Decurtins, S., Häner, R., … Liu, S. X. (2018). Probing Lewis acid-base interactions in single-molecule junctions. Nanoscale, 10(38), 18131–18134. https://doi.org/10.1039/c8nr06562d

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