Abstract
The atmospherically highly relevant methylsulfinyl radical CH3(O)S. was generated thermally under flash pyrolysis conditions and isolated in Ar matrices at 10 K; the allyl radical is a byproduct. CH3(O)S. and its D3- and 13C-isotopologues were characterized through the excellent agreement between experimental and computed IR and UV/Vis spectra. © 2013 The Royal Society of Chemistry.
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CITATION STYLE
APA
Reisenauer, H. P., Romański, J., Mlostoń, G., & Schreiner, P. R. (2013). Matrix isolation and spectroscopic properties of the methylsulfinyl radical CH3(O)S. Chemical Communications, 49(82), 9467–9469. https://doi.org/10.1039/c3cc45379k
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