Probing the solid-liquid interface with tender x rays: A new ambient-pressure X-ray photoelectron spectroscopy endstation at the Swiss Light Source

Abstract

A new endstation to perform operando chemical analysis at solid-liquid interfaces by means of ambient pressure X-ray photoelectron spectroscopy (APXPS) is presented. The endstation is located at the Swiss Light Source and can be attached to the soft X-ray in situ spectroscopy beamline (X07DB) for solid-gas type experiments and to a tender X-ray beamline (PHOENIX I) for solid-liquid interface experiments. The setup consists of three interconnected ultrahigh vacuum chambers: One for sample preparation using surface science techniques, the analysis chamber for APXPS experiments, and an entry-lock chamber for sample transfer across the two pressure regimes. The APXPS chamber is designed to study solid-liquid interfaces stabilized by the dip and pull method. Using a three-electrode setup, the potential difference across the solid-electrolyte interface can be controlled, as is demonstrated here using an Ir(001) electrode dipped and pulled from a 0.1M KOH electrolyte. The new endstation is successfully commissioned and will offer unique opportunities for fundamental studies of phenomena that take place at solid-liquid interfaces and that are relevant for fields such as electrochemistry, photochemistry, or biochemistry, to name a few.