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Efficient asymmetric hydrogenation of imines catalyzed by a neutral iridium(i) complex of (4r,5r)-mod-diop

Chemical and Pharmaceutical Bulletin (1994) 42(9) 1951-1953
DOI: 10.1248/cpb.42.1951
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Abstract

A neutral iridium(I) complex of (4R,5R)-MOD-DIOP (lb) was found to be an efficient catalyst for the asymmetric hydrogenation of imines, A-(a-methylbenzylidene)benzylamine (4) and 2,3,3-trimethylindolenine (6), in the presence of tetrabutylammonium iodide. A high enantioselectivity with up to 81.4% ee was achieved. © 1994, The Pharmaceutical Society of Japan. All rights reserved.

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Morimoto, T., Nakajima, N., & Achiwa, K. (1994). Efficient asymmetric hydrogenation of imines catalyzed by a neutral iridium(i) complex of (4r,5r)-mod-diop. Chemical and Pharmaceutical Bulletin, 42(9), 1951–1953. https://doi.org/10.1248/cpb.42.1951

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