Hybrid microgels containing gold nanoparticles

Abstract

In present paper we report on a preparation of hybrid microgels filled with gold nano-particles (AuNPs). Temperature-sensitive VCL/AAEM microgels have been used as containers for deposition of Au by in situ formation of gold nano-particles. Synthesis of AuNPs has been performed by two methods: a) reduction of chloroauric acid with sodium borhydride and b) reduction of chloroauric acid by sodium citrate under ultrasonic agitation. In both cases AuNPs were deposited directly into microgels leading to formation of composite particles which exhibit temperature-sensitive properties, tunable gold contents and high colloidal stability. The influence of Au load on microgel size, morphology, swelling-deswelling behaviour and stability is discussed.